氨基硅油改*
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{title}:环氧季铵化改*氨基硅油的合成与应用{tag}:0
{journal}:宁波化工
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{pages}:25-28
{date}:2009-09-23
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实验
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{author}:宋
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{title}:活*聚醚对氨基硅油的改*研究
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{title}:亲水*氨基硅油的制备及应用
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{author}:李原刘晶潇万嵘
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{title}:亲水*低黄变氨基改*有机硅乳液的研制{tag}:0
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{title}:亲水*有机硅柔软剂的制备
及其应用
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{title}:水溶*氨基硅油的研制与应用研究{tag}:0
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{title}:水溶*氨基聚硅氧*织物柔软剂的研究{tag}:0
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{title}:织物整理剂改*氨基硅油{tag}:0
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{issue}:6
{pages}:17-19
{date}:2009-09-24
第2篇:*烃基改*硅油的合成及其消泡*能
以*烯*(AA)和1H,1H,2H,2H-全**醇(PFD)为原料合成了*烯**醇酯(AAFDE),用AAFDE与含*硅油(HPS)硅*加成得到*硅油(FPS),确定了合成的较佳工艺条件,同时测定了FPS的表面张力和对柴油体系的消抑泡*能.结果表明,合成AAFDE较佳的工艺条件为:在浓硫*(SA)催化下,*苯为溶剂,n(AA)∶n(PFD)∶n(SA)=1.2∶1∶0.3,反应6h,产率69%.合成FPS较佳的工艺条件为:无溶剂存在条件下,m(AAFDE)∶m(HPS)=1.1∶1,催化剂H2PtCl6的用量为8μg/g(以Pt计),110~120℃反应1h,产率90%.用红外光谱(IR)对AAFDE和FPS进行了分析.25℃下,FPS的表面张力为21.4mN/m,明显低于HPS(22.6mN/m).在柴油中,通过摇瓶法测得合成的FPS比HPS和*基硅油(APS)具有更好的消抑泡*能.
蔡春,王亮,CAIChun,WANGLiang(南京理工大学,化工学院,*苏,南京,210094)
曹治平,CAOZhi-ping(南京四新科技应用研究所有限公司,*苏,南京,210028)
第3篇:八*基环四硅氧*/氨基取代有机硅单体的本体*离子共聚动力学
通过实验分析了八*基环四硅氧*(D4)/N-β-氨乙基-γ-氨*基*基二*氧基硅*(APAEDMS)的本体共聚机理,并结合普适的*离子聚合机制建立了D4/APAEDMS本体共聚速率模型.通过因素(温度、催化剂浓度及原料单体配比)实验考核并完善了所建立的速率模型.研究表明,D4/APAEDMS的本体共聚具有*离子聚合特点,也含有部分逐步聚合行为,在APAEDMS/D4质量比小的情况下,可以用普适的*离子聚合方程进行模型化.